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Are red flowers all red for the same reason?

Science Buddies has an interesting, springtime-themed experiment in the chemistry of color that you can do at home, using plants you've gathered from your yard or a park. It looks like a great activity for curious folks of all ages. Maggie

Why are barns red?

If you've ever spent much time in American farm country, then you've probably noticed that there's a strong tradition there of coating barns and outbuildings with red paint. Why?

Because nuclear fusion.

Okay, the actual answer is simply because red paint has long been a cheap color to buy. But, explains Google engineer Yonatan Zunger, there is some really interesting physics lurking in the background of that price point.

What makes a cheap pigment? Obviously, that it’s plentiful. The red pigment that makes cheap paint is red ochre, which is just iron and oxygen. These are incredibly plentiful: the Earth’s crust is 6% iron and 30% oxygen. Oxygen is plentiful and affects the color of compounds it’s in by shaping them, but the real color is determined by the d-electrons of whatever attaches to it: red from iron, blues and greens from copper, a beautiful deep blue from cobalt, and so on. So if we know that good pigments will all come from elements in that big d-block in the middle, the real question is, why is one of these elements, iron, so much more common than all of the others? Why isn’t our world made mostly of, say, copper, or vanadium?

The answer, again, is nuclear fusion.

You can read the full story on Zunger's Google+ page. In my experience, white is another really common barn color, due to the fact that whitewash — a paint made from calcium hydroxide and chalk (which is also calcium) — is way cheap, as well. Calcium is also one of the most abundant elements in the Earth's crust ... clocking in at number 5, right under iron in the top 10. I'm sure there's some different science that accounts for the high concentrations of calcium on our planet, but the same principal applies. Cheap paint is paint made with abundant (and easily accessible) elements. And abundant elements happen because of physics.

Image: Red Nebraska Barn, a Creative Commons Attribution No-Derivative-Works (2.0) image from 50779843@N03's photostream

Where does "new car smell" come from?

The answer lies in another question. How can PVC — polyvinyl chloride, a commonly used type of plastic — be the stuff that makes tough, rigid sewer pipes and, simultaneously, be the stuff that makes floppy vinyl signs and cheap Goth pants?

"PVC is hard stuff. But if you put in a lot of plasticizer, you can get it to be soft," explains John Pojman, a chemistry professor at Louisiana State University. At a molecular level, PVC is a dense thing. Imagine a slinky in its stiff, compressed state. The plasticizers are chemical compounds derived from coal tar. Mix them with PVC and the small molecules of plasticizer shove their in between the densely packed PVC molecules. Imagine stretching the slinky out so that its coils are now wobbly. Same thing happens here. The more plasticizer you add, the less rigid the PVC.

And it's the plasticizers that produce that smell — the one we associate with the vinyl interior of a new car.

Image: 365:37 - Mar 29 - that new car smell, a Creative Commons Attribution Non-Commercial No-Derivative-Works (2.0) image from waldengirl's photostream

Ammonium nitrate fertilizer isn't really a dangerous explosive (most of the time)

Fertilizer can explode*. We all know that. It was a key ingredient in the bomb that destroyed Oklahoma City's Alfred P. Murrah Federal Building in 1995. Last night, a factory full of the stuff went up with enough force that United States Geological Survey seismographs registered it as a magnitude 2.1 earthquake.

Ammonium nitrate is the chemical that makes these dramatic displays possible. But creating an explosion isn't as simple as just having a pile of ammonium nitrate — let alone a pile of fertilizer — sitting around. We've come to think of this as pretty volatile stuff. But, according to chemist Jimmie Oxley, ammonium nitrate is a lot less dangerous than you might guess. Despite a history of high-profile explosions, like the one that happened last night, ammonium nitrate isn't considered to be that big of a danger. In fact, Oxley called it a "marginal explosive" — a chemical that is mostly safe, but can become dangerous when the conditions are just right.

Read the rest

Read mystery novels to learn chemistry

Deborah Blum — my favorite expert in the fine art of poisoning — writes a fascinating piece about the way mystery writers like Agatha Christie and Dorothy Sayers approached the chemistry in their stories with an almost mind-blowing accuracy. Not only did they get the symptoms of specific poisons correct, they were actually describe common chemical tests and techniques right in the narrative. Maggie

Oceans could yield new sources of rare earth elements

Rare earth elements aren't actually rare, but right now the vast majority of them (97%) come from a single place — China. Given how important these elements are to the making of everything from computers to cars, that gives China quite the monopoly. With that context, here's the news: Japan just found a big supply of rare earth elements in mud at the bottom of the Pacific Ocean. Of course, what may be good news for manufacturing is not necessarily good news for the health of oceans. Maggie

The classy and fascinating back story behind pink champagne

This article at Lapham's Quarterly by Peter Foges has me rethinking my biases against rose champagne — a drink I tend to associate with undergrads and poorly conceived 7-Up cocktails. Turns out, the history (and the chemistry) of rose are totally fascinating. Traditionally the quaff of queens (and really, really, really high-class hookers), real rose is surprisingly difficult to make, relying on a process that could, with just a small error, go wrong and leave you with a drink that is red, brown, or even blue. Maggie

Breast milk is weirder than you think

If you think about lactation too hard, it starts to seem a little strange — like the biological equivalent of saying the word "that" over and over until it's just a weird sound you're making. But, writes Nicholas Day at Slate, the sort of existential weirdness of breast milk is nothing compared to what's going on in the stuff at a chemical level. For instance, breast milk contains sugars that aren't actually digestible by human infants. That's because they aren't meant for the infant, itself. Rather, your breast milk is helpfully feeding your baby's intestinal bacteria. Freakier still: In monkeys, the chemical composition of breast milk can change, depending on factors like your baby's sex and whether your baby is showing signs of illness. Maggie

Grapefruit + prescription drug = overdose

There are 44 prescription drugs on the market today that should never be combined with grapefruit. That's because the sour fruit (and some other, closely related, kinds of citrus) contain chemical compounds called furanocoumarins that prevent your body from metabolizing certain prescription drugs. Essentially, the grapefruit creates an artificial overdose where one tablet packs the power (and side effects) of 20. The CBC has a full list of the drugs, which includes cancer drugs, cholesterol-lowering drugs, and drugs to treat problems of the urinary tract. Wikipedia has more about why this interaction happens. Maggie

The world's tiniest periodic table

Tonight, I got to meet Martyn Poliakoff — the fabulously frizzy-haired University of Nottingham chemist who you might recognize from a series of awesome videos about the periodic table that Xeni first blogged about back in 2008.

This is his business card.

It's a microscope image of the world's tiniest periodic table, which Poliakoff's friends inscribed on a strand of his own hair as a birthday gift in 2010. The hair, which Poliakoff keeps in a glass vial, has earned him a spot in The Guinness Book of World Records.



20130225-095802.jpg

Why your mixer matters

Getting tipsy is more than just a simple equation of "Insert booze, receive stupid behavior". There's some complicated chemistry at work — especially when you begin to factor in the stuff you mix your alcohol into. For instance, the sugar in soda actually prevents your blood stream from absorbing as much alcohol as it otherwise would. Which means, as Allison Aubrey explains at NPR, your choice of mixer could be the difference between a blood alcohol level that is within legal limits and one that is most decidedly not. Maggie

How chili peppers can kill

In the latest "dose makes the poison" news: If you consume enough chili peppers (or even chili powder), it can act as a neurotoxin. Maggie

How snowflakes get their shapes

Not all snowflakes are unique in their shape. There's one fact for you.

And here's another: The shape of snowflakes — whether individually distinct or mass-production common — is determined by chemistry. Specifically, the shape is a function of the temperatures and meteorological conditions the snowflakes are exposed to as they form and the way those factors affect the growth of ice crystals.

This short video from Bytesize Science will give you a nice overview of snowflake production and will help you understand why some snowflakes are unique, and why others aren't.

Chemis-tree


Breokz uploaded a photo of "Xmas at the lab of Avans University of Applied Science." Chemistry may all be "pretty colors and things that go bang," but it sure makes for a festive tree.

True Chemistree (imgur.com)

Molecules with silly names

Meet moronic acid. It's special.

Seriously.

Found in mistletoe and the Chinese sumac, this chemical could be one of the reasons those plants have long been associated with herbal medicine. Scientists studying the anti-viral properties of moronic acid have found it to be effective against HIV and herpes. The HIV work is particularly important, because moronic acid seems to target a different receptor on the virus than other drugs — which means it could be effective against HIV strains that have developed a resistance to existing medication. It'll still be a while before this research translates into a commercial product (if it does at all). But moronic acid is, at least, doing well enough to have made it into Phase II clinical trials — which means that smaller studies on humans have shown that it's generally safe. The Phase II trials, usually done with groups of 100 to 300 people, will help scientists understand whether it's as effective in the human body as it seems to be in the lab.

Looking for more molecules with silly names? Chemist Paul May has a whole list of these things — many of them hilariously immature. List includes arsole, cummingtonite, and fucitol.

Via the Daily Molecule and Deb Blum

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